Dehydration of Benzyl Alcohols in Phosphonium Ionic Liquids: Synthesis of Ethers and Alkenes
نویسندگان
چکیده
منابع مشابه
synthesis of sulfides from alcohols and thiols in solvent-freeconditions and deoxygenation of sulfoxides
کاتالیست یک سنتز جدید برای تیواترها توصیف شده است. واکنش الکل ها با آریل، هتروآریل و آلکیل تیو ل ها درحضور 1،3،5- تری آزو- 2،4،6- تری فسفرین-2،2،4،4،6،6 هگزاکلراید ((tapc به عنوان یک کاتالیست موُثر، بازده های خوب تا عالی از تیواترها را حاصل می کند. علاوه براین، واکنش تحت شرایط بدون فلز و بدون حلال پیش می رود، بنابراین یک مکمل جالب برای روش های شناخته شده سنتز تیواترها ارائه می دهد. یک مکانیسم ا...
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متن کاملFerrocenyl-phosphonium ionic liquids - synthesis, characterisation and electrochemistry.
New unsymmetrically substituted ferrocenyl-phosphonium ionic liquids (ILs) [FcPR2R']NTf2 are synthesized by two or three step syntheses starting from ferrocene, Fc = (C5H5)Fe(C5H4); R = Me, (n)Bu, (n)Hex, Ph; R' = Me, (n)Pr, (n)Bu, Ph; NTf2 = N(SO2CF3)2. The selective synthesis of alkyl phosphines FcPR2via a Friedel-Crafts phosphorylation is highlighted as an alternative for the standard protoc...
متن کاملSilylation of alcohols and phenols by HMDS in the presence of ionic liquid and silica-supported ionic liquids
In this research, different alcohols and phenols are subjected to the reaction with HMDS in the presence of ionic liquid and silica-supported catalysts. Silylation was accomplished under mild reaction conditions at room temperature in short reaction times and good to excellent yields.
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ژورنال
عنوان ژورنال: Advanced Synthesis & Catalysis
سال: 2011
ISSN: 1615-4150
DOI: 10.1002/adsc.201100445